Advancing the Catalytic Frontier: New Horizons in Allylic Amine Synthesis Unveiled in 2022

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The importance of this research area is highlighted by three high-profile papers that appeared over the course of 2022.

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Nickel catalysis: Insights for catalyst selection

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By Valentinos Mouarrawis and Sander Kluwer Catalysis is key for modernizing the chemical industry by making more efficient use of resources and minimizing waste production. The development of efficient catalytic processes is of crucial importance for sustainable-oriented applications, positioning catalysis at the heart of our quality of life. In the fine chemical industry, complex transformations […]

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Nickel solves a long-lasting challenge; An efficient asymmetric hydrogenation of oximes to produce chiral hydroxylamines

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InCatT Blog – new technology to obtain chiral hydroxylamines

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IRON does the job of Ruthenium! Iron-catalyzed ring-opening metathesis polymerization of olefins

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The olefin metathesis reaction is a powerful and widely used catalytic tool to form carbon–carbon double bond. The increasing interest in this reaction in drug discovery and process chemistry is evidenced by the number of commercial applications used at manufacturing scale. Currently, the most applicable catalysts for this transformation are based on ruthenium–carbene complexes. However, […]

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Amine-BF3 salts do the trick. How to introduce tertiary amine in late-stage functionalization?

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How to introduce tertiary amine in late-stage functionalization

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Can Palladium do what the Rhodium-workhorse cannot do? A case of scalable Isoselective hydroformylation

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By: Valentinos Mouarrawis and Sander Kluwer The importance of hydroformylation cannot be overstated! This chemical reaction entails the addition of syngas, a mixture of carbon monoxide (CO) and hydrogen (H2), to olefins in the presence of a catalyst to produce aldehydes. Since its discovery by Otto Roelen in 1938, the hydroformylation process has evolved into […]

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Palladium and Nickel Catalysts in Industry: Opportunities and Challenges.

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By Valentinos Mouarrawis & Sander Kluwer InCatT B.V. Transition metal catalysis occupies a pivotal role in the modernization of our chemical industry because it ensures more efficient use of scarce natural resources and also aids in the minimization of waste production. Besides these economic reasons, the development of efficient catalytic processes is of crucial importance […]

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Tri and tetrasubstituted alkenes are often the starting point, but how to get them

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By Sander Kluwer Alkenes, and particularly substituted alkenes form an important class of compounds are commonly part of biologically active molecules or form the substrate for numerous catalytic conversions such as hydroformylation and (asymmetric) hydrogenation. The synthetic efforts increase with the number of substituents present on the C=C double bond as the possible arrangements increases […]

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Cobalt hydroformylation – The old kid on the block, catching up running

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InCatT blog

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A direct method for carboformylation at last: the acid chloride does the job!

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Aldehydes occupy an important place within the landscape of fine chemicals, notably due to their extensive use in a wide variety of products such as detergents, fragrances, insecticides, etc. The most straightforward type of reactions to produce aldehydes in an atom-efficient manner and direct way lies in the carboformylation of unsaturated compound. Among them, hydroformylation […]

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